Chloe helped TV presenter and Ex-Arsenal goalkeeper, Bob Wilson, start the 24 hour football marathon at Gosfield School, near Halstead, in Essex.
The students will play football right through till 2.30 on Saturday afternoon!
The school will raise many thousands of pounds for the Willow Foundation, a charity that helps seriously ill people aged between 16 - 40.
It was set up by Bob Wilson and his wife Megs in memory of their daughter Anna.
Above: The Mayor of Halstead, David Hume, Chloe and Bob Wilson
Above: Some of the teams before the start with Bob and Chloe